Modifying the pom-pom model for extensional viscosity overshoots

Modifying the pom-pom model for extensional viscosity overshoots

We have developed a variant of the pom-pom model that qualitatively describes two surprising features recently observed in filament stretching rheometer experiments of uniaxial extensional flow of industrial branched polymer resins: (i) Overshoots of the transient stress during steady flow and (ii) strongly accelerated stress relaxation upon cessation of the flow beyond the overshoot. Within th...

Extensional Response of the Pom-pom Model through Planar Contraction Flows for Branched Polymer Melts -part 2 Extensional Response of the Pom-pom Model through Planar Contraction Flows for Branched Polymer Melts -part 2

One objective of this study is to assess the influence of the number of dangling arms at each end of the pom-pom molecule on flow characteristics in a 4:1 planar rounded-corner contraction, where varying the number of arms affects the level of entanglement in the system. For these complex flows, we evaluate the major influence of extensional viscosity and Trouton ratio when comparing kinetic-ba...

Pom-pom like constitutive equations for comb polymers

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POM and Manufacturing

Effect of Elasticity Parameter on Viscoelastic Fluid in Pipe Flow Using Extended Pom-Pom Model

In this study prediction of the steady-state flow of branched polymer melts in pipe geometry with finite volume method is presented. Our analysis in this study revealed that;for normal-stress tqq , the XPP model can predict this tensor unlike the other viscoelastic models such as PTT or Gieskus which can not predict tqq...